Iain,
In my experience, Greater Scaup are more common on Lake Ontario (in the Toronto area) than Lesser. That's particularly true in winter, when virtually all of them are Greater. I would expect to find Lesser at this time of year, but I think they are still less common. You might find a different relative abundance in smaller bodies of water away from Lake Ontario.
All that said, I didn't study the scaup with great care. I was cycling with my young daughter who gets impatient when I stop too long to look at ducks. I based my ID on head shape and the bright white sides.
Brian